ENTRY       EC 1.14.13.51
NAME        6-Oxocineole dehydrogenase
CLASS       Oxidoreductases
            Acting on paired donors with incorporation of molecular oxygen
            With NADH or NADPH as one donor, and incorporation of one atom of
            oxygen
SYSNAME     6-Oxocineole,NADPH:oxygen oxidoreductase
REACTION    6-Oxocineole + NADPH + O2 =
            1,6,6-Trimethyl-2,7-dioxobicyclo-[3.2.2]nonan-3-one + NADP+ + H2O
SUBSTRATE   6-Oxocineole
            NADPH
            O2
PRODUCT     1,6,6-Trimethyl-2,7-dioxobicyclo-[3.2.2]nonan-3-one
            NADP+
            H2O
COMMENT     The product undergoes non-enzymic cleavage and subsequent ring
            closure to form the lactone
            4,5-dihydro-5,5-dimethyl-4-(3-oxobutyl)furan-2(3H)-one.
PATHWAY     PATH: MAP00900  Terpenoid biosynthesis
DBLINKS     University of Geneva ENZYME DATA BANK: 1.14.13.51
            WIT (What Is There) Metabolic Reconstruction: 1.14.13.51
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