ENTRY EC 1.13.11.39
NAME Biphenyl-2,3-diol 1,2-dioxygenase
CLASS Oxidoreductases
Acting on single donors with incorporation of molecular oxygen
(oxygenases)
With incorporation of two atoms of oxygen
SYSNAME Biphenyl-2,3-diol:oxygen 1,2-oxidoreductase (decyclizing)
REACTION Biphenyl-2,3-diol + O2 = 2-Hydroxy-6-oxo-6-phenylhexa-2,4-dienoate
+ H2O
SUBSTRATE Biphenyl-2,3-diol
O2
3-Isopropylcatechol
PRODUCT 2-Hydroxy-6-oxo-6-phenylhexa-2,4-dienoate
H2O
7-Methyl-2-hydroxy-6-oxoocta-2,4-dienoate
COMMENT Also act on 3-isopropylcatechol, forming 7-methyl-2-hydroxy-
-6-oxoocta-2,4-dienoate. Not identical with EC 1.13.11.2.
MOTIF PS: PS00082 [GNTIV]-x-H-x(5,7)-[LIVMF]-Y-x(2)-[DENTA]-P-x-[GP]-
x(2,3)-E
STRUCTURES PDB: 1HAN 1DHY
DBLINKS University of Geneva ENZYME DATA BANK: 1.13.11.39
WIT (What Is There) Metabolic Reconstruction: 1.13.11.39
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