ENTRY EC 1.14.13.51
NAME 6-Oxocineole dehydrogenase
CLASS Oxidoreductases
Acting on paired donors with incorporation of molecular oxygen
With NADH or NADPH as one donor, and incorporation of one atom of
oxygen
SYSNAME 6-Oxocineole,NADPH:oxygen oxidoreductase
REACTION 6-Oxocineole + NADPH + O2 =
1,6,6-Trimethyl-2,7-dioxobicyclo-[3.2.2]nonan-3-one + NADP+ + H2O
SUBSTRATE 6-Oxocineole
NADPH
O2
PRODUCT 1,6,6-Trimethyl-2,7-dioxobicyclo-[3.2.2]nonan-3-one
NADP+
H2O
COMMENT The product undergoes non-enzymic cleavage and subsequent ring
closure to form the lactone
4,5-dihydro-5,5-dimethyl-4-(3-oxobutyl)furan-2(3H)-one.
PATHWAY PATH: MAP00900 Terpenoid biosynthesis
DBLINKS University of Geneva ENZYME DATA BANK: 1.14.13.51
WIT (What Is There) Metabolic Reconstruction: 1.14.13.51
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